Publication Type

Journal Article

Publication Date (Issue Year)

2025

Journal Name

MRS Advances

Abstract

This study explores the structural, mechanical, electronic, lattice dynamical, and thermal properties of the half-Heusler ZrPtSn using first-principles density functional theory. The goal is to assess its suitability for electronic and thermoelectric applications. Structural optimization confirmed stability under ambient conditions. Mechanical properties, including bulk, shear, and Young’s moduli, were evaluated for stiffness and ductility. Electronic structure analysis determined its semiconducting nature, with band gaps of 1.10 eV (without SOC) and 0.95 eV (with SOC). Phonon dispersion was analyzed to assess dynamical stability. ZrPtSn was dynamically stable, with no imaginary phonon modes. Its band gap suggests potential for optoelectronic applications. These findings provide a comprehensive understanding of ZrPtSn’s properties, supporting its potential use in electronic and thermoelectric devices and paving the way for further experimental and theoretical studies.

Keywords

half-Heusler ZrPtSn

Rsif Scholar Name

Lynet Allan

Rsif Scholar Nationality

Kenya

Cohort

Cohort 4

Thematic Area

Energy including Renewables

Africa Host University (AHU)

University of Nairobi (UoN), Kenya

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